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dc.contributor.authorAutorCeledón, Salvador
dc.contributor.authorAutorHamon, Paul
dc.contributor.authorAutorArtigas, Vania
dc.contributor.authorAutorFuentealba, Mauricio
dc.contributor.authorAutorKahlal, Samia
dc.contributor.authorAutorLedoux Rak, Isabelle.
dc.contributor.authorAutorCarrillo, David
dc.contributor.authorAutorSaillard, Jean Yves
dc.contributor.authorAutorManzur, Carolina
dc.contributor.authorAutorHamon, Jean René
dc.date.accessionedFecha ingreso2024-09-03T19:19:11Z
dc.date.availableFecha disponible2024-09-03T19:19:11Z
dc.date.issuedFecha publicación2022
dc.identifier.citationReferencia BibliográficaEuropean Journal of Inorganic Chemistry, 2022(34), 13 p.
dc.identifier.issnISSN1434-1948
dc.identifier.uriURLhttp://repositorio.udla.cl/xmlui/handle/udla/1427
dc.identifier.uriURLhttps://chemistry-europe.onlinelibrary.wiley.com/journal/10990682c
dc.description.abstractResumenThis paper reports on a series of five chiral Schiff base push-pull compounds derived from enantiomerically pure (1R,2R)-(−)-1,2-diaminocyclohexane. The NiII, CuII, ZnII and PdII complexes supported by a ferrocene-containing unsymmetrically-substituted N2O2 quadridentate Schiff base ligand were prepared via template reactions and isolated in 74–87 % yields. A combination of EA, IR, UV/vis and 1H/13C{1H} NMR spectroscopy, HRMS spectrometry, cyclic voltammetry and single-crystal X-ray analysis (for the proligand 2 and its NiII derivative 3), together with computational methods (DFT and TD-DFT) was used to fully characterize and study the properties of all products. Both 2 and 3 crystallize in the orthorhombic non-centrosymmetric space group P212121, with two (R,R)-(−)-chiral carbon atoms in their structure. Second-order nonlinear polarizabilities β have been measured by using Harmonic Light Scattering at 1.91 μm, with the Pd(II) species showing the higher NLO response of 460×10−30 esu.
dc.format.extentdc.format.extent13 páginas
dc.format.extentdc.format.extent2.483Mb
dc.format.mimetypedc.format.mimetypePDF
dc.language.isoLenguaje ISOeng
dc.publisherEditorJohn Wiley and Sons
dc.sourceFuentesEuropean Journal of Inorganic Chemistry
dc.subjectPalabras ClavesChiral Schiff bases
dc.subjectPalabras ClavesDensity functional calculations
dc.subjectPalabras ClavesX-ray diffraction
dc.subject.lcshdc.subject.lcshÓptica no lineal
dc.subject.lcshdc.subject.lcshMetales de transición
dc.titleTítuloExperimental and theoretical evaluation of four NLO-active divalent transition-metal complexes supported by an enantiomerically pure tetradentate schiff base ligand
dc.typeTipo de DocumentoArtículo
dc.udla.catalogadordc.udla.catalogadorCBM
dc.udla.indexdc.udla.indexScience Citation Index Expanded
dc.udla.indexdc.udla.indexScopus
dc.udla.indexdc.udla.indexAcademic Search Ultimate
dc.udla.indexdc.udla.indexApplied Science & Technology Source Ultimate
dc.udla.indexdc.udla.indexChemical Abstracts Core
dc.udla.indexdc.udla.indexChimica
dc.udla.indexdc.udla.indexMaterials Science & Engineering Collection
dc.udla.indexdc.udla.indexMEDLINE
dc.identifier.doidc.identifier.doi10.1002/ejic.202200478
dc.facultaddc.facultadFacultad de Medicina Veterinaria y Agronomía


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